The Barbados native — who was nominated for Best Original Song for her Black Panther: Wakanda Former tune — received multiple shout-outs from winners and presenters throughout the night.
Pitt was popular with the stars who took the stage, earning praise from Brunson, Hall and more. Along with posing for pics with longtime friend Quentin Tarantino, the Babylon actor snapped a selfie with Henry Winkler.
The host made a handful of jokes during the show that raised eyebrows with both guests and viewers — but his Scientology quip earned a collective gasp inside the venue.
Brunson and her ABC costars took home three major wins, including Best Television Series – Musical or Comedy. Throughout the night, the cast was spotted chatting up A-listers from Pitt to Winkler.
The Severance actor — who lost Best Actor in a Television Series – Drama to Yellowstone's Costner — shared a kiss with wife Naomi Scott at their seats.
Before delivering her emotional speech for Best Supporting Actress in a Limited or Anthology Series or Television Film, the White Lotus star had the audience in stitches while presenting an earlier award.
The U.K. native may have ended the night empty-handed, but he proved it truly was just an honor to be nominated. Garfield was spotted catching up with Steven Spielberg, Claire Danes and more throughout the show.